Coffee + chocolate + orange has to be the best flavor combination in the world, although I might make an exception for chocolate + peanut butter or chocolate + cinnamon (I'm sensing a theme.) Starbucks used to have a drink called a Mocha Valencia, which was this blissful combination of mocha and orange. I had an even more favorite version at Coffee People, a place in Portland that has changed hands too many times since the time I loved it - there, they had a Cappuccino Borgia that was a similar flavor combination.
When I looked through One Bowl Baking by Yvonne Ruperti, the recipe for Mocha Valencia Cupcakes really jumped out and grabbed me. She had a similar story - she bemoaned the loss of the Mocha Valencia at Starbucks and tried to recreate it in a cupcake. I had to make them too. The cupcakes are a moist chocolate cake with coffee and orange, and the topping is a rich ganache with all the same flavors. They were a huge hit and I will make them again.
Yvonne Ruperti has worked as a recipe tester and developer at America's Test Kitchen and Cook's Illustrated, and these skills come across in the entire book. Highly recommended!
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